Kinetics and Mechanism of the Decomposition of Chlorous Acid

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Kinetics and Mechanism of the Decomposition of Chlorous Acid

The kinetics of decomposition of aqueous chlorous acid has been reinvestigated at pH 0.7-1.9, ionic strength 1.0 M (HSO4/SO4), and temperature 25.0 ( 0.1 °C. Optical absorbances were collected in the 240-450 nm wavelength range for up to ∼90% decomposition for time series lasting as long as 2 days. The number of absorbing species was investigated by matrix rank analysis; no absorbing intermedia...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry A

سال: 2003

ISSN: 1089-5639,1520-5215

DOI: 10.1021/jp027411h